Single to Multiple Site Behavior of Metallocenes through C–H Activation for Olefin Polymerization: A Mechanistic Insight from DFT
Author:
Affiliation:
1. Polymer Synthesis & Catalysis Group, Reliance Research and Development Center, Reliance Industries Limited, Ghansoli, Navi Mumbai 400701, India
Publisher
American Chemical Society (ACS)
Subject
Catalysis,General Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acscatal.9b03741
Reference44 articles.
1. C–H Activation and Olefin Insertion as Sources of Multiple Sites in Olefin Polymerization Catalyzed by CpAlkylHf(IV) Complexes
2. Zirconocene-Catalyzed Polymerization of α-Olefins: When Intrinsic Higher Activity Is Flawed by Rapid Deactivation
3. Quantification of active sites in single-site group 4 metal olefin polymerization catalysis
4. The Chemistry of Catalyst Activation: The Case of Group 4 Polymerization Catalysts
5. Kinetic and mechanistic aspects of metallocene polymerisation catalysts
Cited by 12 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Capability of isoprene and butadiene as comonomers under metallocene catalysis: Activating active sites with the addition of 1-hexene and propylene;Journal of Catalysis;2024-10
2. Solution Structure and Dynamics of Hf–Al and Hf–Zn Heterobimetallic Adducts Mimicking Relevant Intermediates in Chain Transfer Reactions;Inorganic Chemistry;2024-04-26
3. Mechanism of cationic ring-opening polymerisation of ε-caprolactone using metallocene/borate catalytic systems: a DFT and NCI study on chain initiation, propagation and termination;RSC Advances;2024
4. Mechanism Insights into the Decarbonylation of Furfural to Furan over Ni/MgO: A Molecular Simulation Study;Energy & Fuels;2023-07-10
5. In silico approaches for olefin polymerization using transition metal catalyst systems;In silico Approaches to Macromolecular Chemistry;2023
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3