Au(I)-Catalyzed Formal Intermolecular Carbene Insertion into Vinylic C(sp<sup>2</sup>)–H Bonds and Allylic C(sp<sup>3</sup>)

Au(I)-Catalyzed Formal Intermolecular Carbene Insertion into Vinylic C(sp²)–H Bonds and Allylic C(sp³)–H Bonds

Published:2023-01-11 Issue:3 Volume:13 Page:1554-1561
ISSN:2155-5435
Container-title:ACS Catalysis
language:en
Short-container-title:ACS Catal.

Author:

Cui Xiao-Yuan¹,Ye Zhong-Tian¹,Wu Hai-Hong¹^ORCID,Ji Chang-Ge¹^ORCID,Zhou Feng¹^ORCID,Zhou Jian¹²^ORCID

Affiliation:

1. Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development, and Shanghai Key Laboratory of Green Chemistry and Chemical Process, East China Normal University, Shanghai 200062, China

2. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai 200032, China

Funder

Ministry of Education of the People's Republic of China

Central University Basic Research Fund of China

Science and Technology Commission of Shanghai Municipality

National Natural Science Foundation of China

Publisher

American Chemical Society (ACS)

Subject

Catalysis,General Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acscatal.2c05351

Reference56 articles.

1. Application of donor/acceptor-carbenoids to the synthesis of natural products

2. Gold carbene chemistry from diazo compounds

3. Gold-catalyzed transformations of α-diazocarbonyl compounds: selectivity and diversity

4. Recent Advances in Asymmetric Metal-Catalyzed Carbene Transfer from Diazo Compounds Toward Molecular Complexity

5. Recent progress on donor and donor–donor carbenes

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Stepwise Carbene Transfer Reaction with Alkenes beyond Cyclopropanation;Synthesis;2024-04-09

2. Carbene Formation or Reduction of the Diazo Functional Group? An Unexpected Solvent‐Dependent Reactivity of Cyclic Diazo Imides;Angewandte Chemie International Edition;2023-08-24

3. Carbene Formation or Reduction of the Diazo Functional Group? An Unexpected Solvent‐Dependent Reactivity of Cyclic Diazo Imides;Angewandte Chemie;2023-08-24

4. Chemo- and Diastereoselective Entries into All-Carbon α-Quaternary Aldehydes via C–C Insertion of 4-Diazoisoquinolin-3-ones into C–CHO Bonds;The Journal of Organic Chemistry;2023-07-26

5. Correlation of Experimental and Calculated Reaction Enthalpies with Ligand Donor Strengths;Chemistry – A European Journal;2023-04-03