Efficient Synthesis of α-Allylbutenolides from Allyl Ynoates via Tandem Ligand-Enabled Au(I) Catalysis and the Claisen Rearrangement
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, United States
2. School of Chemical Engineering, Jiangsu Ocean University, Lianyungang, Jiangsu 222005, People’s Republic of China
Funder
Division of Chemistry
Lianyungang Haiyan Project
Jiangsu Overseas Training Program for Universities
Publisher
American Chemical Society (ACS)
Subject
Catalysis,General Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acscatal.9b03501
Reference30 articles.
1. Soft Propargylic Deprotonation: Designed Ligand Enables Au-Catalyzed Isomerization of Alkynes to 1,3-Dienes
2. A general ligand design for gold catalysis allowing ligand-directed anti-nucleophilic attack of alkynes
3. Tertiary Amino Group in Cationic Gold Catalyst: Tethered Frustrated Lewis Pairs That Enable Ligand-Controlled Regiodivergent and Stereoselective Isomerizations of Propargylic Esters
4. One-Pot Synthesis of Benzene-Fused Medium-Ring Ketones: Gold Catalysis-Enabled Enolate Umpolung Reactivity
5. Designed Bifunctional Phosphine Ligand-Enabled Gold-Catalyzed Isomerizations of Ynamides and Allenamides: Stereoselective and Regioselective Formation of 1-Amido-1,3-dienes
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