C(sp3)–F Bond Activation and Hydrodefluorination of the CF3 Group Catalyzed by a Nickel(II) Hydride Complex: Theoretical Insight into the Mechanism with a Spin-State Change and Two Ion-Pair Intermediates
Author:
Affiliation:
1. Element Strategy Initiative for Catalysts and Batteries, Kyoto University, Goryo-Ohara 1-30, Nishikyo-ku, Kyoto 615-8245, Japan
Funder
Core Research for Evolutional Science and Technology
Japan Society for the Promotion of Science
Publisher
American Chemical Society (ACS)
Subject
Catalysis,General Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acscatal.1c02251
Reference83 articles.
1. Kirsch, P. Modern Fluoroorganic Chemistry: Synthesis, Reactivity, Applications; Wiley-VCH: Weinhelm, 2004, pp. 25–169.
2. Fluorine in Pharmaceuticals: Looking Beyond Intuition
3. The Many Roles for Fluorine in Medicinal Chemistry
4. Fluorine in medicinal chemistry
5. C−F Bond Activation in Organic Synthesis
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