Mechanism of Initiation in the Phillips Ethylene Polymerization Catalyst: Redox Processes Leading to the Active Site

Author:

Brown Carole1,Krzystek J.2,Achey Randall1,Lita Adrian1,Fu Riqiang2,Meulenberg Robert W.3,Polinski Matthew1,Peek Nathan1,Wang Youhong4,van de Burgt Lambertus J.1,Profeta Salvatore1,Stiegman A. E.1,Scott Susannah L.4

Affiliation:

1. Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida 32306, United States

2. National High Magnetic Field Laboratory, Tallahassee, Florida 32310, United States

3. Department of Physics and Astronomy, University of Maine, Orono, Maine 04469, United States

4. Department of Chemical Engineering, University of California, Santa Barbara, California 93106, United States

Funder

Basic Energy Sciences

Publisher

American Chemical Society (ACS)

Subject

Catalysis,General Chemistry

Reference60 articles.

1. Hogan, J. P.; Banks, R. L.Polymers and production thereof. U.S. Patent 2825721, March 4, 1958.

2. McDaniel, M. P.InAdvances in Catalysis;Gates, B. C., Knozinger, H., Eds.Elsevier:Amsterdam, 2010; Vol.53, pp123–606.

3. The Structure of Active Centers and the Ethylene Polymerization Mechanism on the Cr/SiO2 Catalyst:  A Frontier for the Characterization Methods

4. McDaniel, M. P.InHandbook of Heterogeneous Catalysis,2nd ed.Ertl, G.; Knozinger, H.; Schuth, F.; Weitkamp, J., Eds.Wiley-VCH:Weinheim, 2008; pp3733–3792.

5. Coordination Environment and Vibrational Spectroscopy of Cr(VI) Sites Supported on Amorphous Silica

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