Electron Spin Echo Envelope Modulation Spectroscopy Reveals How Adenosylcobalamin-Dependent Lysine 5,6-Aminomutase Positions the Radical Pair Intermediates and Modulates Their Stabilities for Efficient Catalysis
Author:
Affiliation:
1. Physics Department, National Dong Hwa University, Hualien 974301, Taiwan
2. Department of Biochemistry, University of Wisconsin−Madison, Madison, Wisconsin 53726, United States
Funder
Ministry of Science and Technology, Taiwan
Publisher
American Chemical Society (ACS)
Subject
Catalysis,General Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acscatal.1c03182
Reference102 articles.
1. Structure–function relationships of radical SAM enzymes
2. Travels with Carbon-Centered Radicals. 5′-Deoxyadenosine and 5′-Deoxyadenosine-5′-yl in Radical Enzymology
3. Radical S-Adenosylmethionine Enzymes
4. The Radical SAM Superfamily
5. Mechanism of Radical Initiation in the Radical S-Adenosyl-l-methionine Superfamily
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1. Non-Aufbau electronic structure in radical enzymes and control of the highly reactive intermediates;Chemical Science;2024
2. The Nitrogen Atom of Vitamin B6 Is Essential for the Catalysis of Radical Aminomutases;International Journal of Molecular Sciences;2022-05-06
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