1. Contribution from the Centro Atómico Bariloche, CNEA, I. Balseiro, UNC & CONICET, Bustillo 9500, R8402AGP Bariloche, Argentina, INIFTA, Depto de Química, UNLP & CONICET, CC. 16-Suc.4, BI904DPI La Plata, Argentina, and Surface Science Western, University of Western Ontario, London, Ontario N6A 5B7, Canada