Reversal Phenomenon of Reaction Velocity in a Mixed Reaction System:  Silylations between Simple Alcohols and α- or β-Hydroxyketones Using Anilinosilanes and Catalytic TBAF Agent

Author:

Iida Akira1,Hashimoto Chihiro1,Misaki Tomonori1,Katsumoto Yukiteru1,Ozaki Yukihiro1,Tanabe Yoo1

Affiliation:

1. Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan tanabe@kwansei.ac.jp

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Reference23 articles.

1. (a) Green, T. W.; Wuts, P. G. M.Protective Groups in OrganicSynthesis, 4th ed.; John Wiley:  New York, 2007; p 172.

2. (b) Kocienski, P.Protecting Groups; Thieme:  Stuttgart, 1994; p 28.

3. Mild, effective and selective method for the silylation of alcohols using silazanes promoted by catalytic tetrabutylammonium fluoride

4. Si-BEZA – catalytic pyridinium triflate: a mild and powerful agent for the silylation of alcohols

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