Reaction of Chromium(V) with the EPR Spin Traps 5,5-Dimethylpyrroline N-Oxide and Phenyl-N-tert-butylnitrone Resulting in Direct Oxidation
Author:
Affiliation:
1. Dartmouth College, Department of Chemistry, 6128 Burke Laboratory, Hanover, New Hampshire 03755-3564
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic9506318
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1. Microsomal reduction of the carcinogen chromate produces chromium(V)
2. Carcinogenic chromium(VI) forms chromium(V) with ribonucleotides but not with deoxyribonucleotides.
3. Chromium(V) can be generated in the reduction of chromium(VI) by glutathione
4. Reaction of Chromium(VI) with Ascorbate Produces Chromium(V), Chromium(IV), and Carbon-Based Radicals
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