Internal Alkyne Isomerization to Vinylidene versus Stable π-Alkyne: Theoretical and Experimental Study on the Divergence of Analogous Cp*Ru and TpRu Systems

Author:

Singh Vinay K.1,Bustelo Emilio1,de los Ríos Isaac1,Macías-Arce Ignacio1,Puerta M. Carmen1,Valerga Pedro1,Ortuño Manuel Ángel2,Ujaque Gregori2,Lledós Agustí2

Affiliation:

1. Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, Facultad de Ciencias, Universidad de Cádiz, 11510 Puerto Real (Cádiz), Spain

2. Departament de Química, Universitat Autònoma de Barcelona, 08193 Bellaterra, Barcelona, Spain

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference99 articles.

1. Metallacumulenes: from vinylidenes to metal polycarbides

2. Bruce, M. I.InMetal Vinylidenes and Allenylidenes in Catalysis;Bruneau, C.; Dixneuf, P. H., Eds.Wiley-VCH:Weinheim, Germany, 2008; pp1–60.

3. Recent Mechanistic and Synthetic Developments in the Chemistry of Transition-Metal Vinylidene Complexes

4. Metal Vinylidenes as Catalytic Species in Organic Reactions

5. Odedra, A.; Liu, R.S.InMetal Vinylidenes and Allenylidenes in Catalysis;Bruneau, C.; Dixneuf, P. H., Eds.Wiley-VCH:Weinheim, Germany, 2008; pp193–214.

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