Synthesis of Digitoxigenin from 3β-[(tert-Butyldimethylsilyl)oxy]-17α-iodo- 5β-androstan-14β-ol via 17β Stereoselective Free-Radical Introduction of γ-Butyrolactone Moiety-Reference-Cited by-同舟云学术

Synthesis of Digitoxigenin from 3β-[(tert-Butyldimethylsilyl)oxy]-17α-iodo- 5β-androstan-14β-ol via 17β Stereoselective Free-Radical Introduction of γ-Butyrolactone Moiety

Published:1997-05-01 Issue:10 Volume:62 Page:3402-3404
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Almirante Nicoletta¹,Cerri Alberto¹

Affiliation:

1. Prassis Istituto di Ricerche Sigma-Tau, Via Forlanini 3, 20019 Settimo Milanese (MI), Italy

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo962237c

Reference11 articles.

1. Synthesis of Digitoxigenin from 3.beta.-Acetoxyandrost-5-en-17-one. Construction of a Suitably Functionalized Pregnane Side Chain via Presumed Allene Oxide Intermediate

2. Total synthesis of rac-9,11-dehydrodigitoxigenin 3-tetrahydropyranyl ether

3. New way to digitoxigenin from 3β-acetoxy-5-androsten-17-one. Stereoselective free radical substitution of iodide atom by nitrile group as a key step

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