A Convenient and General Iron-Catalyzed Hydrosilylation of Aldehydes

Author:

Shaikh Nadim S.1,Junge Kathrin1,Beller Matthias1

Affiliation:

1. Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straβe 29a, D-18059 Rostock, Germany

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference16 articles.

1. For recent reviews on chemo- and enantioselective hydrosilylation:  (a) Carpentier, J.F.; Bette, V.Curr. Org. Chem.2002,6, 913−936. (b) Nishiyama, H.Transition Metals for Organic Synthesis,2nd ed.; Wiley-VCH:  Weinheim, Germany, 2004; Vol. 2, pp 182−191. (c) Nishiyama, H. InComprehensive Asymmetric Catalysis; Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer-Verlag:  1999; Chapter 6.3. (d) Ohkuma, T.; Noyori, R.Comp. Asym. Catal. Supp.2004,1, 55−71. (e) Riant, O.; Mosterai, N.; Courmarcel, J.Synthesis2004, 2943.

2. Cationic Copper(I) Complexes as Efficient Precatalysts for the Hydrosilylation of Carbonyl Compounds

3. Lithium tris(3-ethyl-3-pentyloxy)aluminohydride. A new remarkably chemoselective reagent for the reduction of aldehydes in the presence of ketones

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