Very high chemoselective, regioselective, and E-stereoselective 1,3-chirality transfer involving reaction of acyclic (E)- and (Z)-.gamma.-mesyloxy .alpha.,.beta.-enoates and organocyanocopper-trifluoroborane reagents. Efficient synthetic routes to functionalized chiral .alpha.-alkyl (E)-.beta.,.gamma.-enoates and (E)-allylic alcohols with high optical purity
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Published:1989-06
Issue:13
Volume:111
Page:4864-4872
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ISSN:0002-7863
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Container-title:Journal of the American Chemical Society
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language:en
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Short-container-title:J. Am. Chem. Soc.
Author:
Ibuka Toshiro,Tanaka Miwa,Nishii Shinji,Yamamoto Yoshinori
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Cited by
83 articles.
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