Olefin Metathesis Reactions Initiated by d2 Molybdenum or Tungsten Complexes
Author:
Affiliation:
1. Department of Chemistry 6-331, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om050583r
Reference20 articles.
1. Molybdenum and Tungsten Imido Alkylidene Complexes as Efficient Olefin-Metathesis Catalysts
2. High Oxidation State Multiple Metal−Carbon Bonds
3. Organometallic Complexes of Tantalum That Contain the Triamidoamine Ligand, [(Me3SiNCH2CH2)3N]3-, Including an Ethylidene Complex Formed via a Phosphine-Catalyzed Rearrangement of an Ethylene Complex
4. Dehydrogenation of [{(silox)3Nb}2(η-1,2;η-5,6-C8H8)] (silox=tBu3SiO) to [{(silox)3Nb}2(η-1,2;η-5,6-C8H6)] and Its Subsequent Alkene-to-Alkylidene Rearrangement We thank the US National Science Foundation for support of this research.
5. Thermodynamics, Kinetics, and Mechanism of (silox)3M(olefin) to (silox)3M(alkylidene) Rearrangements (silox = tBu3SiO; M = Nb, Ta)
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