Planar Trimethylenemethane Dianion Chemistry of Lanthanide Metallocenes: Synthesis, Structure, Density Functional Theory Analysis, and Reactivity of [(C5Me5)2Ln]2[μ-η3:η3-C(CH2)3] Complexes-Reference-Cited by-同舟云学术

Planar Trimethylenemethane Dianion Chemistry of Lanthanide Metallocenes: Synthesis, Structure, Density Functional Theory Analysis, and Reactivity of [(C5Me5)2Ln]2[μ-η3:η3-C(CH2)3] Complexes

Published:2006-12-01 Issue:50 Volume:128 Page:16178-16189
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Evans William J.¹,Champagne Timothy M.¹,Ziller Joseph W.¹,Kaltsoyannis Nikolas¹

Affiliation:

1. Contribution from the Department of Chemistry, University of California, Irvine, California 92697-2025, and Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ, United Kingdom

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja0645988

Reference39 articles.

1. Synthetic Utility of [(C5Me5)2Ln][(μ-Ph)2BPh2] in Accessing [(C5Me5)2LnR]x Unsolvated Alkyl Lanthanide Metallocenes, Complexes with High C−H Activation Reactivity

2. Formation of a Bridging Planar Trimethylenemethane Dianion from a Neopentyl Precursor via Sequential β-Alkyl Elimination and C−H Activation

3. Nucleophilic Character of a Charge Neutral, High Oxidation State d0 Zirconium Trimethylenemethane Complex

4. Bis(pentamethylcyclopentadienyl)(η3-trimethylenemethane)zirconium: A New Mode of Bonding for the Trimethylenemethane Ligand

5. Hydrogen-transfer reactions which generate new imine, imido, and trimethylenemethane complexes of tantalum

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