Efficient Transfer Hydrogenation of Ketones Catalyzed by the Bis(isocyanide)−Ruthenium(II) Complexes trans,cis,cis-[RuX2(CNR)2(dppf)] (X = Cl, Br; dppf = 1,1‘-Bis(diphenylphosphino)ferrocene): Isolation of Active Mono- and Dihydride Intermediates
Author:
Affiliation:
1. Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica “Enrique Moles” (Unidad Asociada al CSIC), Facultad de Química, Universidad de Oviedo, E-33071 Oviedo, Spain
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om0400651
Reference44 articles.
1. Asymmetric hydrogen transfer reactions promoted by homogeneous transition metal catalysts
2. trans-[RuCl2(phosphane)2(1,2-diamine)] and Chiraltrans-[RuCl2(diphosphane)(1,2-diamine)]: Shelf-Stable Precatalysts for the Rapid, Productive, and Stereoselective Hydrogenation of Ketones
3. Transfer hydrogenation of ketones with [Ru4H3(CO)12]? as the precatalyst
4. Chemoselective hydrogen-transfer reduction of .alpha.,.beta.-unsaturated ketones catalyzed by isostructural iron(II), ruthenium(II), and osmium(II) cis-hydride (.eta.2-dihydrogen) complexes
5. Transfer Hydrogenation of Carbonyl Compounds Catalyzed by a Ruthenium−Acetamido Complex: Evidence for a Stepwise Hydrogen Transfer Mechanism
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