Variable-Temperature NMR Determination of the Barriers to Rotation about the Ir−C σ-Bond in a Series of Primary Perfluoroalkyl Iridium Complexes [IrCp*{(CF2)nCF3}(PMe3)2]+X- [n = 1, 2, 3, 5, 7, 9, 11; X = I, OTf]-Reference-Cited by-同舟云学术

Variable-Temperature NMR Determination of the Barriers to Rotation about the Ir−C σ-Bond in a Series of Primary Perfluoroalkyl Iridium Complexes [IrCp*{(CF2)nCF3}(PMe3)2]+X- [n = 1, 2, 3, 5, 7, 9, 11; X = I, OTf]

Published:2006-12-13 Issue:2 Volume:26 Page:264-271
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Bourgeois Cheryl J.¹,Huang Hui¹,Larichev Roman B.¹,Zakharov Lev N.¹,Rheingold Arnold L.¹,Hughes Russell P.¹

Affiliation:

1. Departments of Chemistry, 6128 Burke Laboratory, Dartmouth College, Hanover, New Hampshire 03755, and University of California, San Diego, California 92093-0358

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om060822q

Reference29 articles.

1. A conformational analysis of transition metal η1-acyl complexes: steric interactions and stereoelectronic effects

2. Conformational analysis for the pseudooctahedral complexes (.eta.5-C5H5)Fe(CO)(PPh3)CH2R [R = Me, Et, iso-Pr, tert-Bu, SiMe3, (PMe3)+, (PPh3)+, mesityl, Ph, vinyl, 1-naphthyl]: x-ray crystal structures of (.eta.5-C5H5)Fe(CO)(PPh3)CH2R (R = Me, SiMe3)

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