Mechanisms of Bond Cleavage during Manganese Oxide and UV Degradation of Glyphosate: Results from Phosphate Oxygen Isotopes and Molecular Simulations

Author:

Jaisi Deb P.1,Li Hui1,Wallace Adam F.2,Paudel Prajwal1,Sun Mingjing1,Balakrishna Avula1,Lerch Robert N.3

Affiliation:

1. Department of Plant and Soil Sciences, University of Delaware, Newark, Delaware 19716, United States

2. Department of Geological Sciences, University of Delaware, Newark, Delaware 19716, United States

3. USDA-ARS, Cropping Systems and Water Quality Research Unit, Columbia, Missouri 65211, United States

Funder

University of Delaware Research Foundation

National Institute of Food and Agriculture

Office of Experimental Program to Stimulate Competitive Research

University of Delaware

Publisher

American Chemical Society (ACS)

Subject

General Agricultural and Biological Sciences,General Chemistry

Reference56 articles.

1. Mobility and leaching of glyphosate: a review

2. Grube, A.; Donaldson, D.; Kiely, T.; Wu, L.Pesticides industry Sales and Usage: 2006 and 2007 Market Estimates; EPA 733-R-11-001;U.S. Environmental Protection Agency, Office of Chemical Safety and Pollution Prevention (7503P):Washington, DC, 2011; 41pp, available athttp://www.epa.gov/pesticides/pestsales/07pestsales/market_estimates2007.pdf(accessed May 12, 2016).

3. Glyphosate and Its Degradation Product AMPA Occur Frequently and Widely in U.S. Soils, Surface Water, Groundwater, and Precipitation

4. GLYPHOSATE, OTHER HERBICIDES, AND TRANSFORMATION PRODUCTS IN MIDWESTERN STREAMS, 20021

5. The occurrence of glyphosate, atrazine, and other pesticides in vernal pools and adjacent streams in Washington, DC, Maryland, Iowa, and Wyoming, 2005–2006

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