Reactivity of OsH2Cl2(PiPr3)2 toward Diolefins: New Reactions Involving C−H and C−C Activation and C−C and C−P Bond Formation Processes
Author:
Affiliation:
1. Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza−Consejo Superior de Investigaciones Científicas, 50009 Zaragoza, Spain
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om960969p
Reference54 articles.
1. Synthesis, reactivity, molecular structure, and catalytic activity of the novel dichlorodihydridoosmium(IV) complexes OsH2Cl2(PR3)2 (PR3 = P-i-Pr3, PMe-t-Bu2)
2. Structural and Dynamic Properties of OsH2X2L2 (X = Cl, Br, I; L = PiPr3) Complexes: Interconversion between Remarkable Non-Octahedral Isomers
3. An unusual example of hydrogen molecule (H2) coordination by a d4 metal center: reactions between OsH2Cl2(PPr-iso3)2 and H2
4. Distinct structures for ruthenium and osmium hydrido halides: Os(H)3X(PiPr3)2 (X = Cl, Br, I) are nonoctahedral classical trihydrides with exchange coupling
5. Protonation of Chloride in Os(H)2Cl2(PiPr3)2: Synthesis of [(PiPr3)2H2Os(.mu.-Cl)3OsH2(PiPr3)2]CF3SO3
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