New Insights in the Mechanism of Amine Catalyzed Epoxidation: Dual Role of Protonated Ammonium Salts as Both Phase Transfer Catalysts and Activators of Oxone-Reference-Cited by-同舟云学术

New Insights in the Mechanism of Amine Catalyzed Epoxidation: Dual Role of Protonated Ammonium Salts as Both Phase Transfer Catalysts and Activators of Oxone

Published:2003-05-28 Issue:25 Volume:125 Page:7596-7601
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Aggarwal Varinder K.¹,Lopin Chrystel¹,Sandrinelli Franck¹

Affiliation:

1. Contribution from the School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja0289088

Reference35 articles.

1. Jacobsen, E. N.; Wu, M. H.Comprehensive Asymmetric Catalytsis II; Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer-Verlag: Berlin, 1999; pp 649−677.

2. Cation radical cycloadditions and related sigmatropic reactions

3. Hole-catalyzed epoxidation

4. Epoxidation of Alkenes by Amine Catalyst Precursors: Implication of Aminium Ion and Radical Cation Intermediates [J. Am. Chem. Soc. 2000, 122, 8317−8318].

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