Catalytic Dicyanative [4+2] Cycloaddition Triggered by Cyanopalladation of Conjugated Enynes under Aerobic Conditions
Author:
Affiliation:
1. Graduate School of Pharmaceutical Sciences, Chiba University, 1-33, Yayoi-cho, Inage-ku, Chiba, 263-8522, Japan
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja910451j
Reference28 articles.
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2. Regio- and stereo-chemical control in the nickel-catalysed addition of HCN to alkynes. A simple synthesis of (E)-2-alkyl-3-trialkylsilylalk-2-enenitriles
3. Palladium-catalysed addition of trimethylsilyl cyanide to arylacetylenes
4. Palladium- and nickel-catalyzed reaction of trimethylsilyl cyanide with acetylenes. Addition of trimethylsilyl cyanide to the carbon-carbon triple bonds
5. Palladium-catalyzed intramolecular cyanosilylation of alkynes leading to stereoselective synthesis of α,β-unsaturated nitriles
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