1. Department of Inorganic Chemistry, E.T.S. Ingenieros Industriales, Paseo del Cauce s/n, Univrsity of Valladolid, 47011 Valladolid, Spain, and Department of Condensed Matter Physics, Facultad de Ciencias, Prado de la Magdalena s/n, University of Valladolid, 47011 Valladolid, Spain