Two-Center, Three-Center, and Four-Center Dative π-Bonding Systems in Boron−Nitrogen Compounds Studied by Density Functional Theory Calculations: The Molecular Structures of Bis(dimethylboryl)amine, Bis(dimethylboryl)methylamine and Bis(dimethylamino)methylborane Determined by Gas Electron Diffraction
Author:
Affiliation:
1. Department of Chemistry, University of Oslo, Box 1033 Blindern, N-0315 Oslo, Norway
2. Institute of Inorganic Chemistry, Ludwig-Maximillians-Universität München, Butenandtstrasse 7-13, Haus D, D-81377 München, Germany
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om050476x
Reference38 articles.
1. Molecular structure and scaled quantum mechanical force fields of bis(dimethylamino)chloroborane, [(CH3)2N]2BCl, determined by gas-phase electron diffraction and molecular orbital calculations; and supplementary computations for [(CH3)2N]3B, (CH3)2NBCl2, and BCl3
2. Dative σ- and π-bonding in boron–nitrogen compounds: molecular structures of (CH3)2NB(CH3)N(CH3)B(CH3)2 and [(CH3)2B]2NN(CH3)2 determined by gas electron diffraction and quantum chemical calculations
3. Covalent versus Dative Bonds to Main Group Metals, a Useful Distinction
4. Microwave spectrum and molecular structure of aminoborane, BH2NH2
5. Comparative study by single crystal X-ray structure determinations of tetramethylaminoborane and tetramethylethene at 110 K
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