Dynamics and a Unified Understanding of Competitive [2,3]- and [1,2]-Sigmatropic Rearrangements Based on a Study of Ammonium Ylides
Author:
Affiliation:
1. Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, Texas 77842, United States
Funder
National Institutes of Health
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja4128289
Reference26 articles.
1. Stereochemistry of [2,3]-sigmatropic reactions. Wittig rearrangement
2. Thermal racemization of allylic sulfoxides and interconversion of allylic sulfoxides and sulfenates. Mechanism and stereochemistry
3. Simultaneous observation of a radical pathway and retention in a Stevens rearrangement of a sulphonium ylide: significance for a general theory of ylide rearrangements
4. Relation between 1,3- and 1,5-sigmatropic rearrangements of sulfonium ylides
5. Concertedness in [2,3] anionic sigmatropic rearrangements
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