Diarylcarbene Complexes of Chromium from Diazo Precursors:  Synthesis and Reaction with Electron-Rich Alkynes1

Author:

Pfeiffer Jürgen1,Dötz Karl Heinz1

Affiliation:

1. Kekulé-Institut für Organische Chemie und Biochemie, Universität Bonn, Gerhard-Domagk-Strasse 1, D-53121 Bonn, Germany

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference52 articles.

1. [2+1] Cycloadditions of Diazoalkanes to Enol Ethers Catalyzed by Chromium Complexes—The First Direct Spectroscopic Observation of a Carbene Complex Intermediate

2. For reviews see:  (a) Dötz, K. H.; Fischer, H.; Hofmann, P.; Kreissl, F. R.; Schubert, U.; Weiss, K.TransitionMetalCarbeneComplexes; VCH: Weinheim, Germany, 1983. (b) Dötz, K. H.Angew.Chem.Int.Ed.Engl.1984,23, 587. (c) Hegedus, L. S. InComprehensiveOrganometallicChemistryII; Abel, E. W., Stone F. G. A., Wilkinson G., Eds.; Pergamon Press: Oxford, U.K., 1995; Vol. 12, p 549. (d) Wulff, W. D. InComprehensiveOrganicSynthesis; Trost, B. M., Fleming, I., Eds.; Pergamon Press: Oxford, U.K., 1991; Vol. 5, p 1065. (e) Wulff, W. D. InComprehensiveOrganometallicChemistryII; Abel, E. W., Stone, F. G. A., Wilkinson G., Eds.; Pergamon Press: Oxford, U.K., 1995; Vol. 12, p 469. (f) Harvey, D. F., Sigano, D. M.Chem.Rev.1996,96, 271. (g) de Meijere, A.PureAppl.Chem.1996,68, 61. (h) Barluenga, J.PureAppl.Chem.1996,68, 543. (i) Aumann, R.; Nienaber, H.Adv.Organomet.Chem.1997,41, 163.

3. On the Existence of a Tungsten Carbonyl Carbene Complex

4. Übergangsmetall‐Carben‐Komplexe, CII. Pentacarbonyl(acyloxyorganylcarben)‐Komplexe des Chroms(0) und Wolframs(0)

5. Synthesis of cyclobutanones by the photolytic reaction of chromium carbene complexes with olefins: inter- and intramolecular reactions

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