1. Laboratory of Geoenvironmental Science and Engineering, Bradfield Hall, Cornell University, Ithaca, New York 14853-1901, Centre des Sciences de la Terre et de l'Environnement, Université de Bourgogne, 6 Boulevard Gabriel, 21000 Dijon, France, and SIMBIOS Centre, University of Abertay Dundee, Bell Street, Dundee DD1 1HG, UK