A Stable Silylene in a Reactive Environment: Synthesis, Reactivity, and Silicon Extrusion Chemistry of a Coordinatively Unsaturated Ruthenium Silylene Complex Containing Chloride and η3-P−C−P Ligands
Author:
Affiliation:
1. Center for Catalysis Innovation and Research, Department of Chemistry, University of Ottawa, Ottawa, Ontario, Canada K1N 6N5, and Organosilicon Research Center, Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53706
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om0101801
Reference41 articles.
1. Stable Silylenes
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3. Two Trigonal Ni(silylene)3 Complexes
4. Synthesis and Reactivity of (Pentamethylcyclopentadienyl)ruthenium Complexes of the Stable Neutral Silylene Si(tBuNCHCHNtBu)
5. Silylene complexes from a stable silylene and metal carbonyls: synthesis and structure of [Ni{(ButN–CHCH–NBut)Si}2(CO)2], a donor-free bis-silylene complex
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