Effect of the Spinning Motion of the Dihydrogen Ligand on the Properties of an Elongated Dihydrogen Complex. A Theoretical Study of the trans-[Os(H···H)Cl(H2PCH2CH2PH2)2]+ Complex
Author:
Affiliation:
1. Contribution from the Departament de Química, Universitat Autònoma de Barcelona, 08193 Bellaterra, Barcelona, Spain
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja980009p
Reference46 articles.
1. Low-temperature neutron diffraction study of bis(tri-p-tolylphosphine)heptahydridorhenium(VII), [ReH7{P(C6H4CH3-4)3}2]: a polyhydride complex with a short H ? H contact that models an intermediate stage in the oxidative addition of dihydrogen at transition metal centres
2. Reaction of molecular hydrogen (H2) with chlorohydridoiridium phosphines IrHCl2P2 (P = PPr-iso3 or PBu-tert2Ph): stereoelectronic control of the stability of molecular H2 transition metal complexes
3. Determination of the Structure of [Os(.eta.2-H2)en2CH3CO2]PF6 by X-ray and Neutron Diffraction
4. Single Crystal Neutron Diffraction Study of the Complex [Ru(H.cntdot..cntdot..cntdot.H)(C5Me5)(dppm)]BF4 which Contains an Elongated Dihydrogen Ligand
5. Dihydrogen with Frequency of Motion Near the 1H Larmor Frequency. Solid-State Structures and Solution NMR Spectroscopy of Osmium Complexes trans-[Os(H··H)X(PPh2CH2CH2PPh2)2]+ (X = Cl, Br)
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