Solvent Polarity and pH Effects on the Magnetic Properties of Ionizable Nitroxide Radicals: A Combined Computational and Experimental Study of 2,2,5,5-Tetramethyl-3-carboxypyrrolidine and 2,2,6,6-Tetramethyl-4-carboxypiperidine Nitroxides-Reference-Cited by-同舟云学术

Solvent Polarity and pH Effects on the Magnetic Properties of Ionizable Nitroxide Radicals: A Combined Computational and Experimental Study of 2,2,5,5-Tetramethyl-3-carboxypyrrolidine and 2,2,6,6-Tetramethyl-4-carboxypiperidine Nitroxides

Published:2002-10-08 Issue:44 Volume:106 Page:10700-10706
ISSN:1089-5639
Container-title:The Journal of Physical Chemistry A
language:en
Short-container-title:J. Phys. Chem. A

Author:

Saracino Gloria A. A.¹,Tedeschi Annamaria¹,D'Errico Gerardino¹,Improta Roberto¹,Franco Lorenzo¹,Ruzzi Marco¹,Corvaia Carlo¹,Barone Vincenzo¹

Affiliation:

1. Dipartimento di Chimica, Università Federico II, Complesso Universitario Monte S. Angelo, Via Cintia, 80126 Napoli, Italy, Istituto di Biostrutture e Bioimmagini-CNR, Via Mezzocannone 6, 80134 Napoli, Italy, and Dipartimento di Chimica Fisica, Università degli Studi di Padova, Via Loredan 2, 35131 Padova, Italy

Publisher

American Chemical Society (ACS)

Subject

Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jp026492e

Reference31 articles.

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2. Newer aspects of the synthesis and chemistry of nitroxide spin labels

3. Magnetic properties of nitroxide multiradicals

4. Conformational dependence of .beta. hyperfine coupling constants in the nitroxide series

5. The nitrogen hyperfine splitting constant of the nitroxide functional group as a solvent polarity parameter. The relative importance for a solvent polarity parameter of its being a cybotactic probe vs. its being a model process

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