Cationic Acetyl Complexes of Iron(II) and Ruthenium(II) Bearing Neutral N,O Ligands: Synthesis, Characterization, and Interionic Solution Structure by NOESY NMR Spectroscopy
Author:
Affiliation:
1. Dipartimento di Chimica, Università di Perugia, Via Elce di Sotto 8, I-06123 Perugia, Italy, and Institut für Kristallographie und Petrographie, ETH-Zentrum, Sonneggstrasse 5, CH-8092 Zürich, Switzerland
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om980460p
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1. Alkene analogues of bis(N-donor)ketone ligands: ruthenium(II) complexes containing 1-(pyridin-2-yl)-1-(N-methylimidazol-2-yl)ethene and 1,1-bis(N-methylimidazol-2-yl)ethene ((mim)2CCH2), and structural studies of [Ru(bpy)2{(mim)2CCH2}][PF6]2 (bpy=2,2′-bipyridine) and the pyridine-2-carboxylate (pyCO2−) complex [Ru(bpy)2(pyCO2)][PF6]
2. Ethene insertion into a palladium–acetyl bond: crystal structure of [Pd(CH2CH2COMe)(NC5H4CO2Me-2)(PPh3)]BF4, a novel reaction intermediate from the insertion process
3. Preparation of methyl and acetyl complexes of iron(II)
4. Oxidative addition of methyl iodide to monosubstituted and disubstituted derivatives of ruthenium pentacarbonyl: preparation of neutral and ionic complexes of ruthenium
5. Solvent effect on the isotopomerization of (carbonyl-13C)carbonyliodo(methyl)trimethylphosphine)iron: implication on the mechanism of carbon monoxide insertion
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