Nucleation and particle growth with fluctuating rates at the intermediate stage of phase transitions in metastable systems

Author:

Alexandrov D. V.1,Nizovtseva I. G.2

Affiliation:

1. Department of Mathematical Physics, Ural Federal University, Lenin Avenue, 51, Ekaterinburg 620000, Russian Federation

2. Laboratoire des Sciences du Climat et de l'Environnement, Institut Pierre Simon Laplace (LSCE/IPSL CEA), L'Orme des Merisiers, Bat. 701, 91191, Gif sur Yvette Cedex, France

Abstract

An exact analytical solution of an integro-differential model describing the transient nucleation of solid particles (nuclei) and their growth with fluctuating rates at the intermediate stage of bulk phase transitions in metastable systems is constructed. Two important cases of the Weber–Volmer–Frenkel–Zel'dovich and Mier nucleation kinetics are detailed for supercooled melts and supersaturated solutions.

Publisher

The Royal Society

Subject

General Physics and Astronomy,General Engineering,General Mathematics

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