Metal–organic frameworks of the MIL-101 family as heterogeneous single-site catalysts-Reference-Cited by-同舟云学术

Metal–organic frameworks of the MIL-101 family as heterogeneous single-site catalysts

Published:2012-03-14 Issue:2143 Volume:468 Page:2017-2034
ISSN:1364-5021
Container-title:Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences
language:en
Short-container-title:Proc. R. Soc. A.

Author:

Maksimchuk Nataliya V.¹,Zalomaeva Olga V.¹,Skobelev Igor Y.¹,Kovalenko Konstantin A.²³,Fedin Vladimir P.²³,Kholdeeva Oxana A.¹

Affiliation:

1. Boreskov Institute of Catalysis, pr. Lavrentieva 5, Novosibirsk 630090, Russia

2. Nikolaev Institute of Inorganic Chemistry, pr. Lavrentieva 3, Novosibirsk 630090, Russia

3. Department of Inorganic Chemistry, Novosibirsk State University, Pirogova str. 2, Novosibirsk, 630090, Russia

Abstract

In this short review paper, we survey our recent findings in the catalytic applications of mesoporous metal–organic frameworks of the MIL-101 family (Fe- and Cr-MIL-101) and demonstrate their potential in two types of liquid-phase processes: (i) selective oxidation of hydrocarbons with green oxidants—O 2 and tert -butyl hydroperoxide—and (ii) coupling reaction of organic oxides with CO 2 . A comparison with conventional single-site catalysts is made with special attention to issues of the catalyst's resistance to metal leaching and the nature of catalysis.

Publisher

The Royal Society

Subject

General Physics and Astronomy,General Engineering,General Mathematics

Link

https://royalsocietypublishing.org/doi/pdf/10.1098/rspa.2012.0072

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