VIII. Some new experiments and observations on the combustion of gaseous mixtures, with an account of a method of preserving a continued light in mixtures of inflammable gases and air without flame

Abstract

In a Paper read before the Royal Society at their last two meetings, I have described the phenomena of the slow combustion of hydrogene and olefiant gas without flame. In the same paper I have shown, that the temperature of flame is infinitely higher than that necessary for the ignition of solid bodies. It appeared to me, therefore, probable, that in certain combinations of gaseous bodies, for instance, those above referred to, when the increase of temperature was not sufficient to render the gaseous matters themselves luminous; yet still it might be adequate to ignite solid matters exposed to them. I had devised several experiments on this subject. I had intended to expose fine wires to oxygene and olefiant gas, and to oxygene and hydrogene during their slow combination under different circumstances, when I was accidentally led tot the knowledge of the fact , and, at the same time, to the discovery of a new and curious series of phenomena. I was making experiments on the increase of the limits of the combustibility of gaseous mixtures of coal gas and air by increase of temperature. For this purpose, I introduced a small wire-gauze safe-lamp with some fine wire of platinum fixed above the flame, into a combustible mixture containing the maximum of coal gas, and when the inflammation had taken place in the wire-gauze cylinder, I threw in more coal gas, expecting that the heat acquired by the mixed gas in passing through the wire-gauze would prevent the excess from extinguishing the flame. The flame continued for two or three seconds after the coal gas was introduced; and when it was extinguished, that part of the wire of platinum which had been hottest remained ignited, and continued so for many minutes, and when it was removed into a dark room, it was evident that there was no flame in the cylinder.