Akaganeite nanorices deposited muscovite mica surfaces as sunlight active green photocatalyst

Author:

Senthilnathan Anoja12,Dissanayake D. M. S. N.23,Chandrakumara G. T. D.34,Mantilaka M. M. M. G. P. G.23ORCID,Rajapakse R. M. G.15ORCID,Pitawala H. M. T. G. A.36ORCID,Nalin de Silva K. M.27ORCID

Affiliation:

1. Academy of Sri Lanka Institute of Nanotechnology (SLINTEC Academy), Mahenwatte, Pitipana, Homagama 10206, Sri Lanka

2. Sri Lanka Institute of Nanotechnology (SLINTEC), Nanotechnology and Science Park, Mahenwatte, Pitipana, Homagama 10206, Sri Lanka

3. Postgraduate Institute of Science (PGIS), University of Peradeniya, Peradeniya 20400, Sri Lanka

4. Department of Science and Technology, Uva Wellassa University, Passara Road, Badulla 90000, Sri Lanka

5. Department of Chemistry, Faculty of Science, University of Peradeniya, Peradeniya 20400, Sri Lanka

6. Department of Geology, Faculty of Science, University of Peradeniya, Peradeniya 20400, Sri Lanka

7. Department of Chemistry, Faculty of Science, University of Colombo, Colombo 00300, Sri Lanka

Abstract

Thin films of akaganeite [FeO(OH)] nanorices deposited muscovite mica (ANPM) surfaces are synthesized using the facile urea assisted controlled self-assembly technique. The synthesized materials are characterized using scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy, atomic force microscopy, X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy and thermogravimetric analysis (TGA). The prepared nanorices on mica surfaces show average particle length and width of 200 and 50 nm, respectively. Synthesized material acts as an efficient photocatalyst under UV and sunlight conditions as demonstrated by the degradation of standard methylene blue (MB) solution. The MB degradation efficiencies of the catalyst under exposure to 180 min sunlight and UV are 89% and 87.5%, respectively, which shows that the catalyst is more highly active under sunlight than under UV light. Therefore, the synthesized material is a potential green photocatalyst in efficient treatment of industrial dye effluents under direct sunlight.

Funder

National Research Council Sri Lanka

Publisher

The Royal Society

Subject

Multidisciplinary

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