The necessary and the desirable production of radicals in biology

Author:

Abstract

The production of radicals within biological systems can be necessary, as in the coupling of light capture or oxygen-hydride reactions to the generation of proton gradients in thylakoid and mitochondrial membranes; or it can be extremely desirable, to produce an effective catalyst centre in, for example, ribonucleotide reductases. To fit their function the radicals are usually of controlled reactivity, either through their redox properties or through confinement to a limited volume. The more indiscriminate generation of radicals can be of great use too in protective devices, for example, in the production of cross-linked polymers, or in the generation of oxygen radicals. The different distribution and release of initiating enzymes for all these radical processes ensures the spatial and temporal control of their reactions.

Publisher

The Royal Society

Subject

Industrial and Manufacturing Engineering,General Agricultural and Biological Sciences,General Business, Management and Accounting,Materials Science (miscellaneous),Business and International Management

Reference14 articles.

1. Bannister J. V. 1980 Chemical and biochemical aspects of superoxide dismutase. North Holland New York: Elsevier.

2. Burns P. S. Williams R. J. P. & Wright P. E. 1975 Conformational studies of peroxidase-substrate complexes. J.chem. Soc. chem. Commun. pp. 758-759.

3. The detection of intermediates during a B12-dependent enzyme reaction. J.Am. chem;Cockle S. A.;Soc.,1972

4. The biochemical significance of porphyrin Tt-cation radicals. Acct. chem;Dolphin D.;Res.,1974

5. Towards the unification of coenzyme B12-dependent diol dehydratase stereochemical and model studies: The bound radical mechanism

Cited by 26 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3