Alan Herbert Cowley. 29 January 1934—2 August 2020

Author:

Jones Richard A.1,Kemp Richard A.2,Lasch Jonathan G.3,Lattman Michael4,Norman Nicholas C.5

Affiliation:

1. Department of Chemistry, The University of Texas at Austin, Austin, TX 78712, USA

2. Department of Chemistry, University of New Mexico, Albuquerque, NM 87131, USA

3. Alfred E. Mann Institute, University of Southern California, Los Angeles, CA 90018, USA

4. Department of Chemistry, Southern Methodist University, Dallas, Texas 75275, USA

5. School of Chemistry, University of Bristol, Bristol BS8 1TS, UK

Abstract

Alan Cowley was one of the most creative main group chemists of his generation, and had a central role in what was often described as the renaissance of main group chemistry. Throughout his career Alan always had an eye for what was new. In his early years as an independent researcher, Alan made many fundamental contributions to the chemistry of phosphorus, not only in terms of the synthesis of new compounds but also in their study by employing novel analytical and computational methods. Starting in the 1980s he was at the forefront of emerging research into low-coordinate phosphorus chemistry and made seminal contributions in the areas of multiply bonded species, such as phosphenium ions and diphosphenes, as well as in the transition metal coordination chemistry of phosphinidenes. In the second half of his career, Alan also turned his attention to the study of single source precursors for important solid-state electronic materials, many of which were far superior to known examples. In all of the many areas in which Alan worked, he was a great collaborator with colleagues and researchers across the world, both in chemistry and in other disciplines. This was made all the easier by Alan's charm and easy-going nature, which was also manifest in the interactions he had with his many group members over a period of almost half a century. Alan was a gentleman in every sense and is much missed by friends, colleagues, collaborators and family.

Publisher

The Royal Society

Subject

General Medicine

Reference25 articles.

1. Dasent, W. E. 1965 Nonexistent compounds. New York, NY: Marcel Dekker.

2. The first stable transition metal (molybdenum or tungsten) complexes having a metal–phosphorus(III) double bond: the phosphorus analogues of metal aryl- and alkyl-imides; X-ray structure of [Mo(η-C5H5)2(PAr)](Ar = C6H2But3-2,4,6)

3. Turner, D. W. 1970 Molecular photoelectron spectroscopy: a handbook of He 584 Å spectra. London, UK: Wiley-Interscience.

4. Synthesis and structure of bis(2,4,6-tri-tert-butylphenyl)diphosphene: isolation of a true phosphobenzene

5. The halides of niobium and tantalum. Part 5: diethyl ether complexes of the pentachlorides and penta­bromides;Fairbrother F.;J. Chem. Soc.,1958

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