Alan Graham MacDiarmid. 14 April 1927—7 February 2007

Abstract

Alan G. M ac Diarmid was an inorganic chemist by training who pioneered the field of synthetic metals. He grew up in a family that lived frugally, and he had to work in the Chemistry Department of the Victoria University of Wellington as a laboratory assistant before he could undertake part-time degree studies. He was awarded a Fulbright Scholarship to the University of Wisconsin, where he completed his first PhD with Norris Hall. The desire to receive a higher degree in the UK led to a Shell Scholarship to complete a second doctorate with Harry Emeléus FRS. After a sojourn at the University of St Andrews, Alan M ac Diarmid was appointed to an academic position at the University of Pennsylvania, where he remained essentially for his whole career. His early research was based on the properties of silicon hydrides, but he also became interested in poly(sulfur nitride). This led to a search in collaboration with Alan J. Heeger for intrinsically conducting non-metallic materials. A chance meeting with Hideki Shirakawa at the University of Tokyo led to M ac Diarmid being shown thin metallic-like films of poly(acetylene) made in Shirakawa's laboratory. Shirakawa travelled to Philadelphia to collaborate with M ac Diarmid and Heeger on the halogen ‘doping’ of poly(acetylene), which led to the discovery that the doped material was an excellent conductor. Thus, the field of synthetic metals was born. This paradigm-shifting work in which a polymer was shown to be a conductor led to the award of the 2000 Nobel Prize in Chemistry to these three individuals. M ac Diarmid went on to study in great detail the properties of polyaniline; the fact that it could be processed from solution and further modified by oxidative and protonic doping led to all sorts of potentially interesting opportunities in optoelectronics. From all this research, the modern field of organic electronic materials emerged as an important disruptive technology whose advancement depended on an entirely new branch of interdisciplinary science.