Degradation of aniline in water with gaseous streamer corona plasma

Author:

Li Yang1ORCID,Li Zhanguo1,Liu Zhen2,Han Shitong1,Zhao Sanping1,Yan Keping2,Zhu Anna1

Affiliation:

1. State Key Laboratory of NBC Protection for Civilian, Beijing 102205, People's Republic of China

2. Industrial Ecology and Environment Research Institute, Zhejiang University, Hangzhou 310000, People's Republic of China

Abstract

This paper demonstrated the effects and influencing factors in degrading aniline by gaseous streamer corona plasma along water surface under different discharging gas atmospheres. For aniline with an initial concentration of 100 mg l −1 , the degradation was fastest when the reactor was not ventilated, and the degradation rate is 98.5% under 7.5 min treatment. While the degradation was slowest when Ar was ventilated, the degradation rate is 98.6% after treatment for 60 min. Some active particles were detected using a multi-channel fibre-optic spectrometer during the discharge, such as Ar, OH, N 2 , N 2 + and N. In particular, NO was detected during air discharge. The NO and N 2 + could produce NO 3 ; then generated nitric acid would affect the pH value of the solution. The intermediate product by N 2 discharge is nitrophenol, and nitrophenol would be converted to p -benzoquinone. The O 2 discharge could produce an intermediate product of aminophenol. The intermediate products in Ar discharge were in small amounts and the final mineralization effect was the best.

Funder

National Natural Science Foundation of China

Publisher

The Royal Society

Subject

Multidisciplinary

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