The adiabatic invariance of the quantum integrals

Abstract

The postulate of the existence of stationary states in multiply periodic dynamical systems requires that if the condition of such a system, when quantised, is changed in any way by the application of an external field or by the alteration of one of the internal constraints, the new state of the system must also be correctly quantised. It follows that the laws of classical mechanics cannot in general be true, even approximately, during the transition. There is one kind, of change, however, during which one may expect the classical laws to hold, namely, the so-called adiabatic change, which takes place infinitely slowly and regularly, so that the system practically remains multiply periodic all the time. In this case the quantum numbers cannot change, and it should be possible to deduce from the classical laws that the quantum integrals remain invariant. This was attempted by Burgers, who showed that they are invariant provided there are no linear relations of the type Σ r m r ω r = 0 (1) between the frequencies ω r , of the system, where the m r are integers. In general, however, the frequencies will alter during the adiabatic change, and in so doing will pass through an infinity of values for which relations such as (1) hold. A closer investigation is therefore necessary, as was pointed out by Burgers himself. In the following work, conditions which are rigorously sufficient to ensure the invariance of the quantum integrals, are obtained in such a form that it is possible for one to see whether they are satisfied or not without having to integrate the equations of adiabatic motion.