A note on Guggenheim’s theory of strictly regular binary liquid mixtures

Author:

Abstract

This note attempts to revise and extend the formulae proposed by Guggenheim (1935) in his theory of a special (hypothetical) type of liquid mixture which, in the account of Guggenheim’s paper given by Fowler (1936), is called strictly regular. According to the definitions in these sources a binary liquid mixture is said to be strictly regular if (i) there is no volume change on mixing, whatever the relative amounts of the two components, (ii) it possesses a definite co-ordination number, г say, so that each molecule, of either kind, in the liquid has precisely г (nearest) neighbours.

Publisher

The Royal Society

Subject

Pharmacology (medical)

Reference6 articles.

1. Proc;Roy. Soc. A,1935

2. Proc;Camb. Phil. Soc.,1937

3. The Theory of the Liquid State

4. Fowler R . H . 1936 " S tatistical M echanics" 2nd ed. § 13-14. Camb. U niv. Press.

5. Proc. Roy;Guggenheim E .;Soc. A,1935

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