Abstract
It is of considerable interest to investigate the homogeneous unimolecular decomposition of a series of related chemical compounds. The only series so far investigated is that of the aliphatic ethers. On account of their simplicity, low boiling points, and lack of stability, the alkyl nitrites appeared to be worth investigation. The present paper deals with the first member of the series, viz., methyl nitrite. As will be shown, the decomposition of this compound is, in fact, homogeneous and unimolecular.
Experimental Procedure
Reaction velocities were measured in the usual way by observing the rate of pressure change in a system at constant volume. The reaction vessels were pyrex bulbs having a capacity of about 125 cc. The apparatus was similar to those used in a number of previous investigation. The required temperatures were obtained by the use of a well-stirred oil bath, heated electrically. Temperatures were measured with standard mercury thermometers. The temperature could be maintained constant to within 0·25° C.
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