The absorption spectra of carbon dioxide and carbon oxysulphide in the vacuum ultra-violet

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Abstract

The present work follows upon an investigation of the absorption spectrum of carbon disulphide (Price and Simpson 1938) which yielded a spectroscopic value of the ionization potential and certain information about the electronic structure of this molecule. Since the three triatomic molecules CO 2 , COS and CS 2 are closely related, similarities might be expected to occur in their spectra which would facilitate and help to confirm any analysis suggested for the spectrum of a particular molecule. This expectation has to some extent been realized. It will be convenient first to discuss the spectrum of each molecule separately, and then subsequently to draw comparisons between them. The experimental details by which the spectra were obtained have been described in previous articles. They, were photographed with a grazing incidence vacuum spectrograph, the Lyman continuum being used as the continuous background against which the absorption was observed.

Publisher

The Royal Society

Subject

Pharmacology (medical)

Reference8 articles.

1. Die Absorptionsspektren von Kohlendioxyd, Kohlenmonoxyd und Wasserdampf im Gebiet von 600–900 ÅE

2. Henri 1931 Leipziger Vortrage pp. 131-54.

3. Leifson 1926 Astrophys. J. 63 73-89. Lochte-Holtgreven and Bawn 1932 Trans. Faraday Soc. 28 698-704. Mulliken 1935 J . Chem. Phys. 3 720-39. Pauling and Sherman 1933 J. Chem. Phys. 1 606-17. Price 1936 J . Chem. Phys. 4 147-53. Price and Simpson 1938 Proc. Roy. Soc. A 165 272-91. Rathenau 1934 Schmid 1933 Z.Phys. 87 32-56.

4. Z.Phys. 83 711-38.

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