Abstract
Photoelectron spectra are reported for the hydrides of group v and vi elements. Vibrational structure has been observed in bands associated with all but the inner-most valence orbitals. It has been used to obtain changes in bond angles or bond distances which result from the ionization of successive molecular orbitals. Ionization from the inner (la
1
) orbitals of the hydrides has been observed using He II 304 Å+ radiation. From these data vertical ionization potentials have been derived for all the valence orbitals of the hydrides XH, XH
2
, XH
3
and XH
4
for which the corresponding united atoms are Ne, A, Kr and Xe. Graphs of these values are used to show the effects of inner shells on the valence orbitals.
Reference3 articles.
1. Botter R. & Rosenstock H. M. 1967 Advancesin of Petroleum.
2. Ionization and dissociation energies of HF and DF and their bearing on Do0 (F2)
3. Brundle C. R. & Turner D. W. 1968 Spectrometry 4 579. London: Institute
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