Photochemical studies of unimolecular processes IV. Quenching of vibrationally excited cycloheptatriene by added gases-Reference-Cited by-同舟云学术

Photochemical studies of unimolecular processes IV. Quenching of vibrationally excited cycloheptatriene by added gases

Published:1972-08-08 Issue:1577 Volume:329 Page:233-240
ISSN:0080-4630
Container-title:Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences
language:en
Short-container-title:Proc. R. Soc. Lond. A

Author:

Abstract

The relaxation of highly vibrationally excited cycloheptatriene molecules by a variety -of added gases has been studied photochemically. The following mean energies removed per downward step were deduced; He, 1.8; No, 2.4; Ar, 3.5; Kr, 3.6; Xe, 3.3; H 2 , 2.6; D 2 , 2.4; n-C 5 H 12 , 11.7; neo-C 5 H 12 , 10.2 kJ mol -1 . These agree better with data from the ‘fall off’ of unimolecular reactions than with chemical activation studies.

Publisher

The Royal Society

Subject

Pharmacology (medical)

Link

https://royalsocietypublishing.org/doi/pdf/10.1098/rspa.1972.0110

Reference22 articles.

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