Surface energy and surface tension in solids and liquids

Author:

Abstract

Rayleigh’s theory of surface tension, based on the quadrant theorem, is extended to solids and presented in a simple general form.The quadrant theorem is generalized to embrace the traction of a half-space upon a wedge in contact with it, and Young’s equation for the angle of contact is derived as a condition of equilibrium between the surface tension of the liquid and the tangential traction of the solid half-space upon the liquid wedge. The historical theories of capillarity are correlated with the general theory.

Publisher

The Royal Society

Subject

Pharmacology (medical)

Reference7 articles.

1. B akker G. 1899 P r o c . K . A ka d . Wet. A m st. {Sect o f Sci.) 2 (1900) 247-262 (surface tension tre a te d on pp. 259-262) (m eeting 25 N ovem ber 1899); also in Chem. 33 482 (1900).

2. B akker G. 1928 K a p illa rita t u n d O berflachenspannung vol. 6; of Handbuch der m entalphysik (ed. W . W ien an d F . H arm s) Leipzig: A kad. Yerlagsges.

3. Fuchs K . 1889 Sber. A ka d . W iss. W ien 108 A b t. I l a : M ay a n d N ovem ber.

4. On th e equilibrium of heterogeneous substances. T rans;Gibbs J .;Conn. Acad. 3 an d Collected works,1876

5. H erring C. 1951 Surface tension as a m o tiv atio n for sintering. I n The physics of power metallurgy (ed. W . E . K ingston). New Y o rk : M cGraw-Hill.

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