Abstract
The photochemical isomerization of cyclo [1. 3. 5] heptatriene to toluene was studied at seven wavelengths between 228.8 and 313.0 nm. It was shown to occur via a vibrationally excited ground state molecule, the isomerization being quenched by added gases (the parent molecule, toluene, SF
6
, CO
2
, He) according to the Stern-Volmer law. The perdeuteriated compound was also studied.
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