The dielectric behaviour of solutions of some rigid polymers under shear

Author:

Abstract

The variation of the relative permittivity of solutions of ethyl cellulose in benzene and poly- γ -benzyl-L-glutamate (PBLG) in dioxan have been studied in a Couette-type dielectric cell as a function of shear rates (up to 3 x 10 5 s -1 ) and for PBLG also as a function of frequency (400–10 6 Hz). Both systems exhibit a decrease in the low frequency permittivity with shear, tending at the limit of high shear rate to the solvent value for the PBLG system but to a larger value for ethyl cellulose. These observations are analysed in terms of the available theories for the phenomenon. From the analysis estimates for the rotatory diffusion coefficients are obtained which are consistent with dielectric loss measurements. It is suggested that the retention of a contribution of permittivity at high shear rates for ethyl cellulose is due to a polarization normal to the major axis of the macromolecule. The results also provide indications of the overall macromolecular shape of ethyl cellulose and PBLG. The dependence of relative permittivity and loss on frequency and shear rate for PBLG show that the position of the loss peak is shifted to higher frequency by the constraints of a shear field, and that at sufficiently large shear rates the frequency dependence of permittivity exhibits a maximum. Data are also presented on the concentration dependence of shear induced permittivity changes for ethyl cellulose in benzene and the behaviour discussed in terms of polymer–polymer interaction at finite concentrations.

Publisher

The Royal Society

Subject

Pharmacology (medical)

Cited by 17 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Critical parameters to the electrorheological effect;Studies in Interface Science;2005

2. HIGH AC VOLTAGE FLOW-MODIFIED PERMITTIVITY AND RHEOLOGICAL PROPERTIES OF CARBON-DOPED NANO TiO2 ER FLUIDS;International Journal of Modern Physics B;2001-03-20

3. Material Properties and the Electrorheological Response;Annual Review of Materials Science;1993-08

4. Review : Material Aspects of Electrorheological Systems;Journal of Intelligent Material Systems and Structures;1993-01

5. On the observation of micellar structures by dielectric spectroscopy;Colloid & Polymer Science;1991-09

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3