Anomalous reflexions in X-ray patterns

Abstract

The presence on X-ray diffraction patterns of anomalous reflexions, that is to say, reflexions which cannot be accounted for by the simple theory of diffraction, is almost a commonplace. Many of these effects are no doubt to be ascribed to imperfections in the specimen, strains, etc., but even after these have been taken into account there remain streaks and spots for which there is no satisfactory explanation. The observation of effects of the type considered here is by no means novel; Friedrich (1913) recorded them as radial streaks running through the Laue spots in a photograph of KCl. The extra spots are generally very weak compared with the normal Laue reflexions and indeed may not be observed at all unless the photographs are somewhat over-exposed. They are most easily observed on Laue photographs taken with a tube emitting a characteristic radiation such as the K radiation of Cu or Ag, and their study will be greatly facilitated by the use of powerful sources of monochromatic radiation.