Statistical mechanics of binary systems-Reference-Cited by-同舟云学术

Statistical mechanics of binary systems

Published:1942-01-23 Issue:978 Volume:179 Page:340-361
ISSN:0080-4630
Container-title:Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
language:en
Short-container-title:Proc. R. Soc. Lond. A

Author:

Abstract

Mayer’s method for the expansion of the partition function of a gas is adapted to the calculation of the partition function of a binary solid solution. The partition function is expanded in powers of the atomic fraction. Singularities in this expansion correspond to a phase transition. The singularity can be calculated in the simplest case of a binary solution with a two-phase region. This case is treated in full; the limits of solubility and the specific heat are obtained. The latter is discontinuous at the phase boundaries.

Publisher

The Royal Society

Subject

Pharmacology (medical)

Link

https://royalsocietypublishing.org/doi/pdf/10.1098/rspa.1942.0007

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