The free radical polymerization of the vapours of certain vinyl derivatives-Reference-Cited by-同舟云学术

The free radical polymerization of the vapours of certain vinyl derivatives

Published:1946-10-08 Issue:1008 Volume:187 Page:37-53
ISSN:0080-4630
Container-title:Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
language:en
Short-container-title:Proc. R. Soc. Lond. A

Author:

Abstract

The free radical polymerization of the vapours of vinyl chloride, acrylic nitrile, styrene, butadiene and methyl isopropenyl ketone has been investigated using methyl radicals from photo-decomposing acetone. Although all the reactions do not exhibit ideal behaviour it is possible by the application of kinetic methods to measure the ratio of the propagation to the termination coefficients for these polymerization reactions. In this way relative values of the quantitative tendency for a molecule to polymerize by a free radical mechanism can be computed.

Publisher

The Royal Society

Subject

Pharmacology (medical)

Link

https://royalsocietypublishing.org/doi/pdf/10.1098/rspa.1946.0064

Reference6 articles.

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3. Radical Photopolymerization of Vinyl Monomers;Journal of Macromolecular Science, Part C;1982-01

4. Poly(Vinyl Chloride);Organic Chemistry;1977

5. Polymerization of Nitrile Monomers;Organic Chemistry;1974